A popular polymer for custom synthesis is PLGA-PEG-Maleimide. Maleimide operates well as a thiol binding domain allowing customization with your peptide chain. PolySciTech can prepare PLGA-PEG-Maleimide (or PLA, PCL blocks) to your specifications contact me at jg@akinainc.com to discuss your application.
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due to its popularity we have generated a stock product AI03 which is a maleimide endcapped PLGA-PEG http://www.polyscitech.com/products/polyvivo/catalogue.php#Intermediates
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